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Clausius: the mechanical virial relation for bounded stationary motion

Contribution grade

Classical mechanics and statistical physics · Reusable scientific method, experimental result or historical framework

Reference score480,000Provisional editorial estimate of this exact contribution; its grade is assessed separately.

What changed

Particles can keep moving while obeying a simple long-run energy balance. Clausius related the time-averaged kinetic energy of bounded stationary motion to a force-position quantity he called the virial. His mechanical derivation keeps a time-boundary term before taking a periodic or long-time average. For central pair forces and uniform external pressure, it connects microscopic motion with the pressure-volume term.

Scientific scope

Particles can keep moving while obeying a simple long-run energy balance. Clausius related the time-averaged kinetic energy of bounded stationary motion to a force-position quantity he called the virial. His mechanical derivation keeps a time-boundary term before taking a periodic or long-time average. For central pair forces and uniform external pressure, it connects microscopic motion with the pressure-volume term. The stationary setting bounds positions and velocities and requires the relevant averages or periodic averages to be meaningful. A small boundary term alone does not establish existence of every time average or a general ergodic theorem. In the original convention, vis viva is one-half mass times speed squared; the uniform-pressure contribution is 3pV/2. Pair-force and molecular phase-average specializations retain their additional assumptions. This mechanical contribution differs from Clausius entropy theory and later astronomical applications. The source is a contemporary English translation, not a claim of identical German-source bytes.

Evidence

The linked original works support the scoped statement and contribution attribution. WRS has not independently replayed experiments or reconstructed a full mathematical proof. The stationary setting bounds positions and velocities and requires the relevant averages or periodic averages to be meaningful. A small boundary term alone does not establish existence of every time average or a general ergodic theorem. In the original convention, vis viva is one-half mass times speed squared; the uniform-pressure contribution is 3pV/2. Pair-force and molecular phase-average specializations retain their additional assumptions. This mechanical contribution differs from Clausius entropy theory and later astronomical applications. The source is a contemporary English translation, not a claim of identical German-source bytes.

Contributors

Provisional WRS assessment, edition 2026-10-23.5. Independent expert calibration is pending. This grade does not certify correctness or assign ownership.

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