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Zener: transition law for an ideal linear two-level crossing

Two interacting quantum energy levels can avoid crossing even when their uncoupled energies would meet. Zener solved an ideal two-state crossing model to show how the rate of change affects the chance of a non-adiabatic transition. With constant coupling V and a linear uncoupled energy difference of slope s, the asymptotic probability is exp(-2*pi*V^2/(hbar*abs(s))). Slow and fast passages can therefore have very different outcomes.

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Two interacting quantum energy levels can avoid crossing even when their uncoupled energies would meet. Zener solved an ideal two-state crossing model to show how the rate of change affects the chance of a non-adiabatic transition. With constant coupling V and a linear uncoupled energy difference of slope s, the asymptotic probability is exp(-2*pi*V^2/(hbar*abs(s))). Slow and fast passages can therefore have very different outcomes.

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Scientific scope

The exact formula belongs to the ideal all-time linear crossing with fixed coupling and basis states. Applying it to a molecular collision requires the trajectory to be treated as an external parameter and the transition region to justify those approximations. It is not an unrestricted finite-time, noisy or multilevel result. Landau, Stueckelberg and Majorana retain their separate historical contributions; the conditional comparison with Landau reported through an intermediary in this paper is not independent evidence of an error in Landau original. Fowler communicated the paper and is not a coauthor.

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Clarence Zener

Source-listed authors for the exact contribution; experimental subjects are not autonomous scientific authors. Source support and predecessor work retain separate roles. Individual effort shares and unresolved identities are not inferred.

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English catalogue narrative

Zener: transition law for an ideal linear two-level crossing

Two interacting quantum energy levels can avoid crossing even when their uncoupled energies would meet. Zener solved an ideal two-state crossing model to show how the rate of change affects the chance of a non-adiabatic transition. With constant coupling V and a linear uncoupled energy difference of slope s, the asymptotic probability is exp(-2*pi*V^2/(hbar*abs(s))). Slow and fast passages can therefore have very different outcomes.

Scientific scope

The exact formula belongs to the ideal all-time linear crossing with fixed coupling and basis states. Applying it to a molecular collision requires the trajectory to be treated as an external parameter and the transition region to justify those approximations. It is not an unrestricted finite-time, noisy or multilevel result. Landau, Stueckelberg and Majorana retain their separate historical contributions; the conditional comparison with Landau reported through an intermediary in this paper is not independent evidence of an error in Landau original. Fowler communicated the paper and is not a coauthor.

Reading status

This is a source-linked WRS catalogue note. A full explanatory guide and independent scientific reconstruction have not been completed for this entry. Read the identified original work for its complete narrative and arguments.

People and systems

Clarence Zener

Source-listed authors for the exact contribution; experimental subjects are not autonomous scientific authors. Source support and predecessor work retain separate roles. Individual effort shares and unresolved identities are not inferred.

Original sources